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南开大学元素有机重点实验室

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研究队伍

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苗志伟  教授     

Prof. Zhi-Wei Miao (Z.-W. Miao)      

Tel: 86-22-23503192        

E-mail: miaozhiwei@nankai.edu.cn

Group Home Page:    


 

EDUCATION   

1999-2002, Department of Chemistry, Tsinghua University, Beijing, China. Received PhD degree in July, 2002 (with Prof. Yu-Fen Zhao).

1994-1998, Department of Chemistry, Tianjin Normal University. Tianjin, CHINA. Received MS degree in March, 1998 (with Prof. Fang-Ming Miao)

1987-1991, Department of Chemistry, Tianjin Normal University, Tianjin, CHINA. Received BSc degree in July, 1991.


ACADEMIC CAREER                               

2012-present, Professor, Institute of Elemento-organic Chemistry, State Key Laboratory of Elemento-organic Chemistry, Nankai University, Tianjin, CHINA.

2004-2011, Associate Professor, Institute of Elemento-organic Chemistry, State Key Laboratory of Elemento-organic Chemistry, Nankai University, Tianjin, CHINA.

2002-2004, Postdoctoral associate, Department of Chemistry, ETH Zürich, Switzerland (with Prof. Andrea Vasella).

1998-1999, Assistant Professor, Department of Chemistry, Tianjin Normal University, Tianjin, CHINA.


RESEARCH AREA

(1)     Organic phosphorus chemistry and Asymmetric synthesis chemistry

(2)     Applied organic chemistry and Agriculture chemistry


HONORS AND AWARDS 
2014, Award for “Xinjiang Tianshan Scholar” (the Xinjiang Uygur Autonomous Region of China)

2018, Award for “Nankai University Teaching Famous Teacher Award”

2024, Award for “Minjiang Scholar” (the Fujian province of China)


PROFESSIONAL MEMBERSHIPS

2022-  Member, Chemical Fertilizer Professional Committee of China Chemical Society.

2024-  Member of the Phosphorus Chemistry Professional Committee of the 31st Council of the Chinese Chemical Society


Representative Achievements

Selected Publications (2021-present)

  1. Xiyuan Zhang, Bo Jang, Yang Yang, Rui Dong, Jiapeng Ding, and Zhiwei Miao* “Synthesis of Furans/Pyrroles through Palladium-Gold Relay Catalyzed Skeletal Editing of Carbonates or Carbamates via a Decarboxylative-Aromatization Strategy” Adv. Synth. Catal. 2025, 367, e202500198.

  2. Tianyu Li, Danqing Wu, Linlin Xu, Jiajun Liu, Yin Yang, Zhiwei Miao* and Dazhen Xu* “Copper-Catalyzed Oxidative Arylation and Hydroxylation of Indolin-2-ones for Direct Construction of Tetrasubstituted Carbon Centers” J. Org. Chem. 2025, 90, 960-970.

  3. Xingyu Tu, Bo Jiang, Hongming Fang, Yiyang Qiao, and Zhiwei Miao* “Syntheses of Phosphonylated Pyrido-dihydrofurans by Regioselective 5-exo-dig Addition to Carbon-carbon Triple Bond Catalyzed by AgNO3” J. Org. Chem. 2024, 89, 13876-13885.

  4. Jiaming Xu, Yanfeng Gao, Xin Gao, and Zhiwei Miao* “Diastereoselective Synthesis of Dearomatic 2-oxa-7-azaspiro[4.5]decane Derivatives through Gold and Palladium Relay Catalytic Tandem Cyclization of Enynamides with Vinyl Benzoxazinanones” Adv. Synth. Catal. 2024, 366, 4778-4785.

  5. Yuankun Wang,# Yintong Zhao,# Shu Zhang, Long Shang, Youxuan Ni, Yong Lu, Yixin Li, Zhenhua Yan,* Zhiwei Miao,* and Jun Chen* “Monofluorinated Phosphate with Unique P-F Bond for Nonflammable and Long-Life Lithium-Ion Batteries” Angew. Chem. Int. Ed. 2024, doi.org/10.1002/anie.202412108.

  6. Fengxiao Wang, Xiyuan Zhang, Jiaming Xu, Qitao Shen, Bo Jiang, and Zhiwei Miao* “Metal-free visible-light-induced direct synthesis of alkyl-substituted phosphonodithioates from white phosphorus (P4)” Adv. Synth. Catal. 2024, 367, e202401355.

  7. Jing Huang, Yushuang Liang, Shengnan Sun, Ruilong Zhang, and Zhiwei Miao* “Silver-catalyzed Tandem Cycloisomerization/[5 + 2] Cycloaddition of 3-Cyclopropylideneprop-2-en-1-ones with Oxidopyrylium Ylides to Form Bibridged Benzocycloheptanones” J. Org. Chem. 2023, 88, 8454-8464.

  8. Yanfeng Gao, Hui Wang, Xiaoquan Chen, Yiyang Qiao, and Zhiwei Miao* “Gold and Palladium Relay Catalytic [4 + 4] Cycloadditions of Enynamides and γ-Methylene-δ-valerolactones: Diastereoselective Construction of Furan-fused Azacyclooctanes” J. Org. Chem. 2023, 88, 11822-11833.

  9. Yanfeng Gao, Xuange Zhang, Xiyuan Zhang, and Zhiwei Miao* “Catalytic Asymmetric Construction of 1,2,4-Benzotriazepine Skeleton via Diastereo- and Enantioselective Decarboxylative [4+3] Cyclization” Org. Lett. 2021, 23, 2415-2420.

  10. Yanfeng Gao, Yuanhao Mao, and Zhiwei Miao* “Enantioselective 1,3-Dipolar (5+3) Cycloadditions of Oxidopyrylium Ylides and Vinylcyclopropanes Towards 9-Oxabicyclononanes” Org. Lett. 2022, 24, 3064-3068.

  11. Xiyuan Zhang, Cong Zhang, Bo Jiang, Yanfeng Gao, Xiufang Xu*, and Zhiwei Miao* “Ligand-controlled Palladium-catalyzed Asymmetric [4+3] and [2+3] Annulation Reactions of Spirovinylcyclopropyl Oxindoles with o-Quinone Methides” Org. Lett. 2022, 24, 3097-3101.

  12. Zhenhao Gao, Juan Xie, Hong Huang, Zhiwei Miao* “Preparation and thermal properties of a novel DOPO-based Schiff base derivative as a flame retardant for polystyrene” J. Appl Polym Sci. 2022; e52702.

  13. Jing Huang, Bo Jiang, Xiyuan Zhang, Yanfeng Gao, Xiufang Xu, and Zhiwei Miao* “Triethyamine-promoted [5+3] Cycloadditions for Regio- and Diastereoselective Synthesis of Functionalized aza-Bicyclo[3.3.1]alkenones” Adv. Synth. Catal. 2022, 364, 3622-3628.

  14. Yanfeng Gao, Xuange Zhang, Xiyuan Zhang, and Zhiwei Miao* “Catalytic Asymmetric Construction of 1,2,4-Benzotriazepine Skeleton via Diastereo- and Enantioselective Decarboxylative [4+3] Cyclization” Org. Lett. 2021, 23, 2415-2420.

  15. Xiyuan Zhang, Yanfeng Gao, Yitong Liu, and Zhiwei Miao* “Diastereoselective Synthesis of Tetrabenzohydrofuran Spirooxindoles via Diethylphosphite-mediated Coupling of isatins with ortho-Quinone Methides” J. Org. Chem. 2021, 86, 8630-8640.