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南开大学元素有机重点实验室

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研究队伍

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孙忠明 教授  博士生导师    

Prof. Zhong-Ming Sun (Z.-M. Sun)                

E-mail: sunlab@nankai.edu.cn

Group Home Page: https://mse.nankai.edu.cn/szm/list.htm      


 

Education   

2001-2006   Physical Chemistry from Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences. Received PhD degree in June, 2006.  

1997-2001    Department of Applied Chemistry,  Wuhan University , CHINA. Received BSc Degree in June, 2001.  

 

Academic Career                                

2018-            Professor in Nankai University 

2010-2018    Professor in Changchun Institute of Applied Chemistry, Chinese Academy of Sciences (CIAC).

2008-2010    Postdoctoral Associate in North Dakota State University. Advisor: Professor Pinjing Zhao.

2006-2008    Postdoctoral Associate in Pacific Northwest National Laboratory Advisor: Professor Lai-Sheng Wang.


Research Areas

(1)    Naked Metal clusters, Zintl cluster, Main group chemistry

(2)    Metal-metal bond


Honors & Awards 
(1) Award for National Excellent Young Scientist (National Natural Science Foundation of China)

(2) Award for Young Pioneer (Chinese Academy of Sciences Changchun Branch)


Selected Publications

  1. Yu-He Xu, Wen-Juan Tian, Alvaro Munoz-Castro, Gernot Frenking, Zhong-Ming Sun*

    "An all-metal fullerene: [K@Au12Sb20]5-"

    Science, 2023, 382(6672), 840-843. Highlighted by C&EN

  2. Xu-Hui Yue, Wei-Xing Chen, Tao Yang, Alvaro Muñoz-Castro, Gernot Frenking, Zhong-Ming Sun*

    Carbon-free sandwich compounds based on Arsenic and Antimony with icosahedral  metal cores

    Nature Synth., 2023, 2, 423-429

  3. Wei-Qiang Zhang, Zi-Sheng Li, John E. McGrady,* Zhong-Ming Sun*

    Synthesis and Characterization of [Fe3(As3)3(As4)]3–, a Binary Fe/As Zintl Cluster Containing an Fe3 Core

    Angew. Chem. Int. Ed. 2023, e202217316

  4. Zi-Chuan Wang, Lei Qiao, Zhong-Ming Sun*, Manfred Scheer. 

    Inorganic Ferrocene Analogue [Fe(P4)2]2- 

    J. Am. Chem. Soc. 2022, 144, 6698-6702 (JACS spotlight, ACS Editors' Choice, highlighted by Chemistry World, ChemistryViews, Nature Synthesis)

  5. Harry W. T. Morgan, Cong-Cong Shu, Zhong-Ming Sun*, John E. McGrady*

    A missing link in the growth of lead-based Zintl clusters: isolation of the dimeric plumbaspherene [Cu4Pb22]4–

    J. Am. Chem. Soc. 2022, 144, 8007-8017

  6. Hong-Lei Xu, N. V. Tkachenko, D. W. Szczepanik, I. A. Popov, A. Muñoz-Castro, A. I. Boldyrev,* Zhong-Ming Sun*

    Symmetry Collapse due to the Presence of Multiple Local Aromaticity in [Ge24]4-

    Nature Commun. 2022, 13, 2149 (Feature Article)

  7. Yi Wang, John E. McGrady, Zhong-Ming Sun*

    Solution-Based Group 14 Zintl Anions: New Frontiers and Discoveries

    Acc. Chem. Res. 2021, 54, 1506-1516

  8. Yu-He Xu, Nikolay V. Tkachenko, Ivan A. Popov, Lei Qiao, Alvaro Muñoz-Castro, Alexander I. Boldyrev, Zhong-Ming Sun*.

    Ternary aromatic and anti-aromatic clusters derived from the hypho species [Sn2Sb5]3−

    Nature Commun., 2021, 12, 4465.

  9. Hong-Lei Xu, Nikolay V. Tkachenko, Alvaro Muñoz-Castro, Alexander I. Boldyrev*, Zhong- Ming Sun*.

    [Sn8]6--bridged mixed-valence Zn(I)/Zn(II) in {[K2ZnSn8(ZnMes)]2}4- Inverse Sandwich-Type Cluster Supported by Zn(I)-Zn(I) Bond.

    Angew. Chem. Int. Ed., 2021, 60, 9990-9995.

  10. Hong-Lei Xu, Nikolay V. Tkachenko, Zi-Chuan Wang, Wei-Xing Chen, Lei Qiao, A. Muñoz- Castro, A. I. Boldyrev*, Zhong-Ming Sun*.

    A Sandwich-Type Cluster Containing Ge@Pd3 Planar Fragment Flanked by Aromatic Nonagermanide Caps.

    Nature Commun., 2020, 11, 5286. (Feature Article)

  11. Lei Qiao, Chao Zhang, Cong-Cong Shu, Harry Morgan, John E. McGrady*, Zhong-Ming Sun*.

    [Cu4@E18]4– (E=Sn, Pb): Fused Derivatives of Endohedral Stannaspherene and Plumbaspherene.

    J. Am. Chem. Soc., 2020, 142(31), 13288–13293.

  12. Hong-Lei Xu, Ivan A. Popov, Nikolay V. Tkachenko, Zi-Chuan Wang, Alvaro Muñoz- Castro, A.I. Boldyrev,* Zhong-Ming Sun*.

    σ-Aromaticity-Induced Stabilization of Heterometallic Supertetrahedral Clusters [Zn6Ge16]4– and [Cd6Ge16]4–.

    Angew. Chem. Int. Ed., 2020, 59, 17286–17290. (Hot Paper)

  13. Cong-Cong Shu, Harry W. T. Morgan, Lei Qiao, John E. McGrady*, Zhong-Ming Sun*.

    A family of lead clusters with precious metal cores.

    Nature Commun., 2020, 11, 3477. (Feature Article)

  14. Chao Liu, N. V. Tkachenko, I. A. Popov, N. Fedik, Xue Min, C.-Q. Xu, Jun Li, J. E. McGrady, A. I. Boldyrev, Zhong-Ming Sun*

    Structure and Bonding in [Sb@In8Sb12]3− and [Sb@In8Sb12]5−.

    Angew. Chem. Int. Ed., 2019, 58, 8367-8371. (Inside Cover)

  15. Ivan A. Popov, Fu-Xing Pan, X.-R. You, Lei-Jiao Li, E. Matito, C. Liu, H.-J. Zhai, Zhong- Ming Sun,* and Alexander I. Boldyrev*.

    Peculiar All-Metal sigma-Aromaticity of the [Au2Sb16]4- Anion in the Solid.

    Angew. Chem. Int. Ed., 2016, 55(49), 15344–15346.

  16. Xue Min, Ivan A. Popov, Fu-Xing Pan, Lei-Jiao Li, Eduard Matito, Zhong-Ming Sun,* Lai-Sheng Wang, Alexander I. Boldyrev*.

    All-Metal Antiaromaticity in Sb4-Type Lanthanocene Anions.

    Angew. Chem. Int. Ed., 2016, 55(18), 5531-5535. (For a highlight of this paper, see: Ritter, S. K. “Cyclic antimony complexes take aromaticity to a new level, Chemical & Engineering News, 2016, 94, P5)

  17. Fu-Xing Pan, Lei-Jiao Li, Ying-Jin Wang, Jin-Chang Guo, Hua-Jin Zhai*, Li Xu, and Zhong-Ming Sun*.

    An All-Metal Aromatic Sandwich Complex [Sb3Au3Sb3]3-.

    J. Am. Chem. Soc., 2015, 137, 10954-10957. (For a highlight of this paper, see: Ritter, S. K. “All-Metal Sandwich Is Now On The Menu，Chemical & Engineering News 2015,93 (34) 24. This article was also featured as a JACS spotlight)

  18. Jing Zhang, Jun-Feng Liu, Angel Ugrinov, Anthony F. X. Pillai, Zhong-Ming Sun*, Pinjing Zhao*

    Methoxy-Directed Aryl-to-Aryl 1,3-Rhodium Migration

    J. Am. Chem. Soc. 2013, 135 (46), 17270–17273