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南开大学元素有机重点实验室

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仇友爱   特聘研究员  博士生导师    

Prof. You-Ai Qiu (Y. Qiu)        

Tel: 17502215086        

E-mail: qiuyouai@nankai.edu.cn

Group Home Page: https://www.x-mol.com/groups/qiu_youai            


 

Education   

2010-2015    Department of Chemistry, Zhejiang University, China. Received Ph.D. degree in June, 2015 (with Prof. Shengming Ma).  

2003-2007    Department of Chemical Engineering & Technology, China University of Mining and Technology. Received B.Sc. degree in July, 2007 (with Prof. Xianyong Wei)


Academic Careerd

2020-           Professor (tenure-track), State Key Laboratory of Elemento-organic Chemistry, College of Chemistry,Nankai University, 

                    Tianjin, China.

2019-2020   Visiting Researcher, RIKEN, Wako, Japan (With Prof. Zhaomin Hou, JSPS Fellowship).

2017-2019   Postdoctoral Researcher, Institute of Organic and Biomolecular Chemistry, Georg-August-University Göttingen, 

                    Germany (with Prof. Lutz Ackermann).

2015-2017   Postdoctoral Researcher, Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University, Sweden 

                    (with Prof. Jan-Erling Bäckvall).

2007-2009   R&D Engineer, J&K Chemical (Suzhou), China.


Research Areas

(1)     Green Organic Chemistry: Organic Electrosynthesis

(2)     Transition-metal Catalysis and Organocatalysis

(2)     Small-molecule Activation and Radical Chemistry


Honors & Awards 
2021    Funded by National Natural Science Foundation of China (NSFC)

2020    Nankai University Hundred Young Academic Leaders Program

2019    JSPS Fellowship

2015    Outstanding Graduate of Zhejiang University



Selected Publications

Research Summary: My research interests are in the area of organic synthesis, organic electrocatalysis, asymmetric catalysis, heterogeneous catalysis, and transition metal-catalyzed cascade transformations. During past several years, more than 30 papers were published as first authors or corresponding authors, among those, 4 in JACS, 7 in Angew. Chem., 1 in CCS Chem., 1 in Acc. Chem. Res., and 1 in Chem. Sci. Selected publications were listed as followed.


  1. T. Feng, S. Wang, Y. Liu, S. LiuY. Qiu*, Electrochemical Desaturative β-Acylation of Cyclic N-Aryl Amines, Angew. Chem. Int. Ed. 2022, 61, e202115178 (VIP, Very Important paper) (Selected as a Frontispiece).

  2.  M.-B. Li, A. K. Inge, D. Posevins, K. P. J. Gustafson, Y. Qiu*, J.-E. Bäckvall*, Chemodivergent and Diastereoselective Synthesis of γ-Lactones and γ-Lactams: A Heterogeneous Palladium-Catalyzed Oxidative Tandem Process, J. Am. Chem. Soc. 2018, 140, 14604. (Highlighted by Synfacts, 2019, 15, 0230.)

  3. B. Yang, Y. Qiu*, J.-E. Bäckvall*, Control of Selectivity in Palladium(II)-Catalyzed Oxidative Transformations of Allenes, Acc. Chem. Res. 2018, 51, 1520.

  4. D. Posevins, Y. Qiu*, J.-E. Bäckvall*, Highly Diastereoselective Palladium-Catalyzed Oxidative Carbocyclization of Enallenes Assisted by a Weakly Coordinating Hydroxyl Group, J. Am. Chem. Soc. 2018, 140, 3210. (Highlighted by Synfacts, 2018, 14, 0518.)

  5. Y. Qiu*+, D. Posevins+, J.-E. Bäckvall*, Selective Palladium-Catalyzed Allenic C–H Bond Oxidation for the Synthesis of [3]Dendralenes, Angew. Chem. Int. Ed. 2017, 56, 13112.

  6. Y. Qiu+, A. Scheremetjew+, L. Ackermann*, Electro-Oxidative C–C Alkenylation by Rhodium(III) Catalysis, J. Am. Chem. Soc. 2019, 141, 2731.

  7. Y. Qiu+, M. Stangier+, T. H. Meyer, J. C. A. Oliveira, L. Ackermann*, Iridium-Catalyzed Electrooxidative C–H Activation by Chemoselective Redox-Catalyst Cooperation, Angew. Chem. Int. Ed. 2018, 57, 14179. (Highlighted by Synfacts, 2019, 15, 0018.)

  8. Y. Qiu+, W. Kong+, J. Struwe, N. Sauermann, T. Rogge, A. Scheremetjew, L. Ackermann*, Electrooxidative Rhodium-Catalyzed C–H/C–H Activation: Electricity as Oxidant for Cross-Dehydrogenative Alkenylation, Angew. Chem. Int. Ed. 2018, 57, 5828. (Highlighted in ChemistryViews)

  9. Y. Qiu, C. Tian, L. Massignan, T. Rogge, L. Ackermann*, Electrooxidative Ruthenium-Catalyzed C–H/O–H Annulation by Weak O-Coordination, Angew. Chem. Int. Ed. 2018, 57, 5818.

  10. Y. Qiu, B. Yang, T. Jiang, C. Zhu, J.-E. Bäckvall*, Palladium-Catalyzed Oxidative Cascade Carbonylative Spirolactonization of Enallenols, Angew. Chem. Int. Ed. 2017, 56, 3221.

  11. Y. Qiu, B. Yang, C. Zhu, J.-E. Bäckvall*, Highly Selective Olefin-Assisted Palladium- Catalyzed Oxidative Carbocyclization via Remote Olefin Insertion, Chem. Sci. 2017, 8, 616.

  12. Y. Qiu, B. Yang, C. Zhu, J.-E. Bäckvall*, Highly Efficient Cascade Reaction for Selective Formation of Spirocyclobutenes from Dienallenes via Palladium-Catalyzed Oxidative Double Carbocyclization-Carbonylation-Alkynylation, J. Am. Chem. Soc. 2016, 138, 13846.

  13. Y. Qiu, B. Yang, C. Zhu*, J.-E. Bäckvall*, Palladium-Catalyzed Oxidative Carbocyclization- Borylation of Enallenes to Cyclobutenes, Angew. Chem. Int. Ed. 2016, 55, 6520.

  14. Y. Qiu+, C. Zhu+, M. Stangier, J. Struwe, L. Ackermann*, Rhodaelectro-Catalyzed C–H and C–C Activation, CCS. Chem. 2020, 2, 1529.

  15. D. Posevins, M.-B. Li, E. S. Grape, A. K. Inge, Y. Qiu*, J.-E. Bäckvall*, Highly Diastereoselective Palladium-Catalyzed Oxidative Cascade Carbonylative Carbocyclization of Enallenols. Org. Lett. 2020, 22, 417.