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南开大学元素有机重点实验室

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张弛  教授  博士生导师

   Prof. Chi Zhang (C. Zhang)

   Tel: 86-22-13370398727

   E-mail: zhangchi@nankai.edu.cn

 

  
EDUCATION

1996-2001

Ph.D., Department of Chemistry, The University of Hong Kong
Hong
Kong
, China (with Prof. Dan Yang).
1993-1996

M.S.Department of Chemistry, Lanzhou UniversityLanzhou,
C
hina (with Prof. Xin-Fu Pan).
1986-1990

B.S., Department of Chemistry, Lanzhou UniversityLanzhou,
C
hina.

 

  ACADEMIC CAREER

2003-Date              Professor, State Key Laboratory of Elemento-organic Chemistry, Nankai UniversityTianjin, China.

2001-2003              Postdoctoral associate, Department of Chemistry, Stanford University, U.S.A. (with Prof. James P. Collman).


RESEARCH AREAS

    (1)   Synthetic Methodologies.

    (2)   Hypervalent Iodine Chemistry.

    (3)   Fine Chemicals Synthesis.

    (4)   Total Synthesis of Natural Products.

 

   HONORS AND AWARDS

2007      Award for New Century Excellent Talents in University (Ministry of Education of China)

 

   SELECTED PUBLICATIONS

  1.  Recent Advances in Hypervalent Iodine ChemistryY.-N. Duan, S. Jiang, Y.-C. Han, B. Sun, C. Zhang *, Chin. J. Org. Chem.201636, 1973-1984.

  2.  Practical peptide synthesis mediated by a recyclable hypervalent iodine reagent and tris(4-methoxyphenyl)phosphineC. Zhang*, S.-S. Liu, B. Sun, J. TianOrgLett. 2015, 17, 4106-4109.

  3.  Recyclable hypervalent-iodine-mediated dehydrogenative α,β′-bifunctionalization of β-keto esters under metal-free conditions, Y.-N. Duan, L.-Q. Cui, L.-H. Zuo, C. Zhang*Chem. Eur. J. 201521, 13052-13057.

  4.  Iodosodilactone as a recyclable oxidant for efficient oxidation of alcohols to carbonyl compounds, A. Song, C. Zhang*Acta Chim. Sinica 201573, 1002-1006.

  5.  Boron trifluoride etherate functioning as a fluorine source in an iodosobenzene-mediated intramolecular aminofluorination of homoallylic amines, J. Cui, Q. Jia, R.-Z. Feng, S.-S. Liu, T. He, C. Zhang*Org. Lett. 2014, 16, 1442-1445.

  6.  Synthesis of oxazolidin-2-ones and imidazolidin-2-ones directly from 1,3-diols or 3-amino alcohols using iodobenzene dichloride and sodium azide, T. He, W.-C. Gao, W.-K. Wang, C. Zhang*Adv. Synth. Catal. 2014356, 1113-1118.

  7.  Iodine-mediated intramolecular amination of ketones: the synthesis of 2-acylindoles and 2-acylindolines by tuning N-protecting groups, W.-C. Gao, S. Jiang, R.-L. Wang, C. Zhang*Chem. Commun. 201349, 4890-4892.

  8.  Practical oxazole synthesis mediated by iodine from α-bromoketones and benzylamine derivatives, W.-C. Gao, R.-L. Wang, C. Zhang*Org. Biomol. Chem. 201311, 7123-7128.

  9.  Recyclable hypervalent iodine(III) reagent iodosodilactone as an efficient coupling reagent for direct esterification, amidation, and peptide coupling, J. Tian, W.-C. Gao, D.-M. Zhou, C. Zhang*Org. Lett. 2012, 14, 3020-3023.

  10.  A mild and efficient direct α-amination of β-dicarbonyl compounds using iodosobenzene and p-toluenesulfonamide catalyzed by perchlorate zinc hexahydrate, J. Yu, S.-S. Liu, J. Cui, X.-S. Hou, C. Zhang*Org. Lett. 2012, 14, 832-835.

  11.  A dramatic solvent effect on one-pot synthesis of substituted ureas directly from primary alcohols using the combined reagent of iodobenzene dichloride and sodium azide in ethyl acetate, C. Zhang*, W.-K. Wang, T. He, Synthesis 201244, 3006-3014.

  12.  A simple and effective synthesis of benzolactones and benzolactams by noncatalytic benzylic oxidation of cyclic benzylic ethers and N-protected cyclic benzylic amines with sodium chlorite as an oxidant, A.-R. Song, J. Yu, C. Zhang*Synthesis 201244, 2903-2909.

  13.  Design, synthesis, structure, and dehydrogenation reactivity of a water-soluble o-iodoxybenzoic acid derivative bearing a trimethylammonium groupL.-Q. Cui, Z.-L. Dong, K. Liu, C. Zhang*Org. Lett. 2011, 136488-6491.

  14.  Effective oxidation of benzylic and alkane C-H bonds catalyzed by sodium o-iodobenzenesulfonate with Oxone as a terminal oxidant under phase-transfer conditions, L.-Q. Cui, K. Liu, C. Zhang*, Org. Biomol. Chem. 201192258-2265.

  15.  Enantioselective α-tosyloxylation of ketones catalyzed by spirobiindane scaffold-based chiral iodoarenes, J. Yu, J. Cui, X.-S. Hou, S.-S. Liu, W.-C. Gao, S. Jiang, J. Tian, C. Zhang*Tetrahedron: Asymmetry. 201122, 2039-2055.

  16.  One-pot synthesis of symmetrical 1,3-diarylureas or substituted benzamides directly from benzylic primary alcohols and effective oxidation of secondary alcohols to ketones using phenyliodine diacetate in combination with sodium azide, X.-Q. Li, W.-K. Wang, Y.-X. Han, C. Zhang*Adv. Synth. Catal. 2010, 3522588-2598.

  17.  Various α-oxygen functionalizations of β-dicarbonyl compounds mediated by the hypervalent iodine(III) reagent p-iodotoluene difluoride with different oxygen-containing nucleophiles, J. Yu, J. Tian, C. Zhang*, Adv. Synth. Catal. 2010352, 531-546.

  18.  A simple and effective method for α-hydroxylation of β-dicarbonyl compounds using Oxone as an oxidant without a catalyst, J. Yu, J. Cui, C. Zhang*Eur. J. Org. Chem. 2010, 7020-7026.

  19.  One-pot synthesis of carbamoyl azides directly from primary alcohols and oxidation of secondary alcohols to ketones using iodobenzene dichloride in combination with sodium azide, X.-Q. Li, W.-K. Wang, C. Zhang*Adv. Synth. Catal. 2009351, 2342-2350.

  20.  A safe, convenient and efficient one-pot synthesis of α-chloroketone acetals directly from ketones using iodobenzene dichloride, J. Yu, C. Zhang*Synthesis 2009, 2324-2328.

  21.  An environmentally benign TEMPO-catalyzed efficient alcohol oxidation system with a recyclable hypervalent iodine(III) reagent and its facile preparation, X.-Q. Li, C. Zhang*Synthesis 2009, 1163-1169.

 


 

 

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